Organotransition metal chemistry from bonding to catalysis pdf download

Organotransition metal chemistry from bonding to catalysis pdf download

Organotransition metal chemistry from bonding to catalysis pdf download,Frequently bought together

Organotransition Metal Chemistry – From Bonding to Catalysis provides a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the Phosphane ligands are well-known in organometallic chemistry and catalysis, and the application of methoxy-substituted triarylphosphanes has also been re- ported, [1] [2] [3] 13/09/ · University Science Books, Sausalito pp., hardcover, $ —ISBN Library of Congress Cataloging-in-Publication Data Hartwig, John, Organotransition metal chemistry: from bonding to catalysis / John Hartwig. p. cm. Includes bibliographical Organotransition metal chemistry from bonding to catalysis pdf download The book uses the covalent model in describing both bondings made in most organometallic compounds and ... read more

Erik J. Alexanian 98 98 3. Structure of Enolate Complexes 58 98 3. Spectral Features of Enolate 59 2. Complexes of Neutral Oxygen Donors 2. Complexes of Neutral Sulfur Donors Complexes 62 3. Synthesis of Enolate Complexes 63 3. Cyanide Complexes Written with 64 2. Overview of Sigma Complexes 2. Dihydrogen Complexes 97 3. Enolate Complexes Written with 3. Overview 2. Pyridine and Imine Complexes 2. Sigma Complexes 57 57 57 2. Dinitrogen Complexes 95 96 3. Alkynyl Complexes 53 2. Complexes of Ligands Bound Through N, O and S 2. Amine Complexes 94 3. Vinyl Complexes Written with Prof. Complexes of Organic Carbonyl r 6-Arene 92 3. Complexes with Bridging Aryl Ligands 2. Physical and Chemical Properties of Alkyne Compounds 92 3.

Synthesis of Complexes Containing Terminal 51 Ligands Prof. Jesse W. Tye 64 3. Overview 66 2. Properties tint Lead to Stable H, Complexes 67 3. Properties of the Free Molecule 2. Spectroscopic Signatures ofH2 Complexes 67 3. Structures and Electron Counting of Metal- 2. Reactivity of H, Complexes 68 2. Alkane and Silane Complexes 70 Cyanide Complexes 2. Evidence for Allcane Complexes 3. Synthesis of CN" Complexes 70 3. Allyl, if-Benzyl, Pentadienyl, and 73 Dr. Mark J. Pouy 3. Allyl Ligands Chapter 3. Covalent X-Type Ligands Bound Through Metal-Carbon and Metal-Hydrogen Bonds 85 3. Overview 3. Introduction 3. Dynamics of Metal-Allyl Complexes 85 3. Reactions of Allyl Complexes 3. r 4-Trimethylenemethane TMM Complexes 86 3. Thermodynamic Properties 3. Cyclopentadienyl and Related Compounds ofM-Alkyl Written with Prof. Norton 86 3. Synthesis of Metal-Alkyl Complexes 87 3.

Synthesis of Alkyl Complexes by Transmetallation r 3-Benzyl 3. Higher Anionic iT-Ligands 3. History of Transition Metal-Alkyl Bonds 3. Structures of Allyl Ligands 3. Synthesis of tt-Allyl Complexes 85 3. Alkyl Ligands Written with Prof. Norton Trimethylenemethane Ligands Written with 71 3. Transition Metal Hydrocarbyl Ligands 3. Spectral Features of M - C N Complexes 70 2. Intramolecular Coordination of Aliphatic C-H Bonds Agostic Interactions 3. Thermodynamics of M-CN Linkages 2. Stability Relative to H2 Complexes References and Notes 90 3. Aryl, Vinyl, and Alkynyl Complexes Written 51 Complexes 89 3. Selected Reactions of Metal-Alkyl Complexes 2. Spectral Properties of Metal-Olefin 2. Alkyne Complexes 88 3. Synthesis of Alkyl Complexes by 87 3. Bonding and Thermodynamics of Cp Ligands CONTENTS 4. Thermodynamic Properties of 3. Seth B. Herzon 3. Structures of "Sandwich Complexes" 4. Overview Metal-Amido Complexes 3.

Other Modes of Binding of Cyclopentadienyl Cyclopentadienyl Ligand 4. Synthesis of Early-Metal-Amido Complexes Complexes 4. Amidate and Amidinate Complexes of the 3. Reactions of Cyclopentadienyl Complexes Early Transition Metals Written with Prof. Hydride Ligands Written by Prof. Complexes of Anionic Nitrogen Heterocycles 3. Structural Features Written with Prof. Jianrong Steve Zhou 3. Terminal Hydrides 4. Bridging Hydrides 4. Metal-Azolyl Bonding 3. Spectroscopic Properties 3. From Hydrogen 3. From Main Group Hydrides 3. From Other Reagents 4. Overview 4. Properties of the Free Molecule 3. Acidities of Hydride Complexes 4. Structures and Electron Counting of Metal-Nitrosyl Complexes 4.

Thermodynamics of M-NO linkages 3. Hydrogen Bonding 4. Synthesis of NO Complexes 4. Reactivity of Chapter 4. Covalent X-Type Ligands Bound Through Metal-Heteroatom Bonds 4. Complexes Containing Metal-Nitrogen Bonds 4. Metal-Amido Complexes Prof. Pinjing Zhao Metal-Nitrosyl 4. Polydentate Nitrogen Donor Ligands Complexes Written with 4. Bonding of Late-Metal-Amido 4. Structures of Metal-Porphyrin Complexes of the Late Transition-Metals Complexes Written with Giang Vo 4. Overview of Metal-Amido Complexes Complexes Complexes 4. Organometallic Porphyrin and Corrin 4. Late-Metal-Amido 4. Spectral Features of M-NO Complexes 4. Overview and Scope 4. Reactivity of Metal-Azolyl Complexes Prof.

Tye 3. Strength of M - H Bonds 4. Nitrosyl Complexes Written with 3. ByProtonation 4. Synthesis of Metal-Azolyl Complexes 3. Synthesis of Metal-Hydride Complexes References and Notes 4. Reactivity of Early-Metal-Amido 3. Ligands That Are Electronically Similar to the 3. Hydricities 4. Thermodynamic Properties of Early- 3. Bent Metallocenes Cp2MLx and Related Norton 4. Amido Complexes of the Early Transition Metals 3. Reactivity of Late-Metal-Amido 3. CpjM and Their Permethyl Derivatives Compounds 4. Synthesis of Late-Metal-Amido 3. Spectral Properties of Late-Metal- 3. Examples of Substituted Cyclopentadienyl 3. Ansa Metallocenes xxiii 4. Synthesis of Metal-Porphyrin Complexes 4.

Reactivity of Metal-Porphyrin Complexes XXii CONTENTS 4. Bis-Sulfonamide Complexes Written with Prof. Walsh 4. Bonding of Late-Metal Alkoxides 4. Bonding in Bis-Sulfonamido Complexes 4. Thermodynamics of Late-Metal-Alkoxo Bonds 4. Synthesis of Bis-Sulfonamide Complexes Ligands 4. Thermodynamics of 4. Pyrazolylborate Ligands Written with Complexes Complexes Ligands and Complexes Dr. Jaclyn M. Murphy 4. Reactions of Polypyrazolylborate Complexes 4. Structure and Bonding of B-Diketiminate Complexes 4. Transition Metal Complexes with Anionic Oxygen Ligands Written with Prof. Pinjing Zhao 4. Transition Metal-Alkoxo Complexes 4. Reactivity of Metal-Boryl Complexes 4. Structures of Phosphido Complexes 4. Dynamics of Phosphido Complexes 4. Thermodynamic Properties of Phosphido 4. Reactivity of Phosphido Complexes 4. Transition Metal-Thiolate-Complexes Written with Dr. Elsa Alvaro 4. Overview Alkoxides Complexes 4. Reactivity of Thiolate Complexes Dr.

Tim A. Boebel 4. Early-Metal Alkoxides as Ancillary 4. Electronic Properties of Free and Coordinated Properties 4. Transition-Metal-Silyl Complexes Written with 4. Reactivity of Early-Metal-Alkoxo 4. Stericand 4. Synthesis of Metal-Thiolate Complexes 4. Preparation of Early-Metal-Alkoxo Complexes 4. Thermodynamics of M-SR Bonds Complexes 4. Bonding and Structures of Transition-Metal-Thiolate 4. Bonding of Early-Metal Silyl Groups Electronic Early-Metal-Alkoxo 4. Structures of Metal-Silyl Complexes Complexes 4. Alkoxide Complexes of the Late Transition Complexes 4. Synthesis of Metal-Silyl Complexes 4. Stability and Reactivity of Silyl 4. Spectral Properties of Metal-Silyl 4. Catalytic Reactions of 4. Synthesis of Metal-Boryl Complexes Complexes 4. Alkoxide Complexes of the Early Transition Metals Written with Prof.

Norton 4. Examples of 3-Diketiminate Ligands 4. Transition-Metal-Phosphido Complexes 4. Synthesis of 3-Diketimines and Metals 4. Thermodynamics of Metal-Boryl 3-Diketiminate Ligands 4. Metal-Boryl Bonding 4. Transition-Metal-Boryl Complexes Written with 4. Synthesis of Polypyrazolylborate Complexes 4. Metal 3-Diketonate Complexes 4. Catalytic Reactions of Late-Metal-Alkoxo 4. Bonding of Polypyrazolylborate Complexes Complexes 4. Reactivity of Late-Metal-Alkoxo Ligands 4. Preparation of Late-Metal-Alkoxo Metal-Bis-Sulfonamido Bonds 4. Late-Metal Alkoxides as Ancillary Dr. Murphy Complexes CONTENTS 4. Halide Ligands 4. Overview 5. Substitutions of Electron Complexes that Deviate from Pure Thermally Induced 4. Steric and Electronic Properties Dissociative Mechanisms 4. Reactivity of Metal-Halide Complexes References and Notes an Associative Term in the Rate Law 5. Overview of Ligand Substitution Reactions Electron Transfer Initiated by Atom Abstractions 5.

The Basic Factors that Control Ligand Ligands Substitutions Electron and Electron Complexes Bimetallic and Higher Nuclearity Clusters 5. Dependence of the Rates on the 5. Summary Incoming Ligand, the Departing Substitutions 5. Dissociative Substitution Reactions 6. Definition of Oxidative Addition Ligand Substitution Examples of Dissociative Substitutions 5. Stereochemistry of Dissociative Substitution 2 36 5. Substitution of Weakly Bound Ligands in 5. Electronic Effect of Ancillary Ligands on the Substitution Reactions—The Cis Effect 6. Examples of Oxidative Addition of H2 to a 5. Steric Effects on Dissociative Substitution Electron Complexes 6.

General Mechanism for the Oxidative Addition of H2 5. Reactions ofNi CO 4 as Quintessential 5. Stereochemistry of Substitutions of Octahedral 6. Thermodynamics of Oxidative Addition 6. Oxidative Addition of Dihydrogen 5. General Features of the Kinetics of Dissociative Compounds Chapter 6. Oxidative Addition of Nonpolar Reagents 6. Qualitative Trends for Oxidative Addition 5. Substitution Reactions of EIectron Complexes Rates of Dissociative 6. Definitions, Examples, and Trends References and Notes 5. Associative Substitutions of Electron Complexes 5. Ligand Substitutions in Metal-Metal Bonded of Square-Planar Complexes Ring Slip 5.

The Rate Law for Associative 5. Associative versus Dissociative 5. Associative Substitution by Pentadienyl Ligand 5. Trans and Cis Effects Reactions Substitution and Cis-Trans Ligand, and the Metal Center Ligands 5. Substitutions for Dienes and Trienes 5. Substitutions for Arenes and Arene Exchange 5. Stereochemistry of Associative Substitutions 5. Substitution Reactions Involving Polyhapto 5. Associative Substitutions of Square-Planar ds Isomerization 5. Other Assisted Ligand 5. Mechanisms of Ligand Substitutions of Complexes 5. Oxidation of Coordinated CO 5. Mechanisms of Ligand Substitutions 5. Photoinduced Dissociation of 5.

Thermochemical Considerations 5. Ligand Substitutions by Radical Chains 5. Scope of the Chapter 5. Ligand Substitution Catalyzed by 5. Definitions of Associative, Dissociative, and Substitution Mechanisms 5. Catalyzed and Assisted Ligand Substitution Interchange 5. Substitutions ofM CO e Complexes Occur with Chapter 5. Ligand Substitution Reactions 5. Introduction xxiii Single Metal Center 6. Oxidative Addition of H2 to Two Metal Centers 6. Oxidative Addition of Silanes 6. Oxidative Addition of C-H Bonds 6. Early History of C - H Bond Oxidative Addition 6.

Intramolecular C-H Oxidative Addition 6. Intermolecular Oxidative Addition of C - H Bonds CONTENTS XXii 6. Selectivity of Alkane Oxidative Addition 6. Mechanism of Oxidative Addition of C - H Bonds Density 6. Synthetic Applications of C - H Oxidative Addition of Alkyl Groups Complexes Without Oxidation and Reduction Reductive Elimination Formation 8. Overview and Principles 8. Examples Complexes 6. Oxidative Addition of E-E Bonds 8. Evidence for Intermediate Alkane and Arene 6. Oxidative Addition of C-C Bonds 8. Reductive Eliminations Organized by Type of Bond Bonds 6. Potential Sigma-Bond Metatheses Involving Late Transition Metal Complexes Induced 8. Reductive Elimination to Form C-H 6. Sigma-Bond Metathesis Involving d° 6. Summary 8. The Effect of Coordination Number 8. The Effect of Light: Photocliemically 6.

Dinuclear Activation of Hydrocarbons Multiple Bonds 8. Tlie Effect of Participating Ligands 8. The Effect of Geometry 6. Addition of H-H and C-H Bonds to Transition Metal Complexes 8. Tlie Effect of Steric Properties 6. Examples of Complexes that Oxidatively Add Alkanes 8. Effect of Metal Identity and Electron 8. The Effect of Ancillary Ligands on C-H Bond-Forming Reductive Elimination 8. Reductive Elimination to Form X-H References and Notes Bonds 8. Reductive Elimination to Form C - C Bonds Chapter 7. Oxidative Addition of Polar Reagents 7. Introduction 8. The Effect of Bite Angle 8. Survey of Carbon-Carbon 7. Inner-Sphere Electron Transfer and Caged Radical Pairs 7. Radical Chain Pathways Reductive Eliminations Form C-X Bonds Resulting Radical with a Second Metal 7. Concerted Oxidative Additions C-X Bonds C - X Bonds from Arylpalladium II Complexes 8.

Reductive Eliminations to Form C - X Bonds from Acyl Complexes 8. Summary Chapter 8. Reductive Elimination 8. Changes in Electron Count and Oxidation Chapter 9. Migratory Insertion Reactions 8. Factors that Affect the Rates of Reductive 9. Description of Migratory Insertion and Elimination Elimination 9. Overview and Basic Principles References and Notes 8. Reductive Eliminations to Form 7. Dinuclear Oxidative Additions of Electrophilic State Alkylplatinum IV Complexes 7. Oxidative Addition of Reagents with H - X References and Notes C - X Bonds from Aryl and with C - X Bonds of Medium Polarity 8. Overview 8. Concerted Oxidative Additions of Reagents 7.

Summary Bond-Forming 8. Survey of Reductive Eliminations to Form 7. Atom Abstraction and Combination of the A-B 8. Mechanisms of Reductive Eliminations to Bonds o f Medium Polarity 8. Reductive Elimination to Form C - X Bonds 7. Outer-Sphere Electron-Transfer Mechanisms 8. The Effect of Coordination Number 7. Oxidative Additions by One-Electron 8. The Effect of Participating Groups 7. Oxidative Addition by SN2 Pathways Mechanisms 8. Trends and Principles 9. Changes in Geometry and Electron Count During Migratory Insertion and Elimination CONTENTS 9. Specific Classes of Insertions 9.

Insertions of Aldehydes and Imines 9. Insertions of Ligands Bound by a Single Atom 9. Summary d8 9. Stereochemistry at Carbon 9. Stereochemistry at the Metal Chemistry 9. Redox Acceleration 3-Hydrogen Elimination Bonds 9. Insertions of Olefins into Metal 9. Insertions of Alkynes into Metal 9. Insertion of Ketones and Imines into 9. Insertions of Olefins into Metal-Carbon Metal-Hydrocarbyl cr-Bonds 9. Insertions of Olefins into Metal-Acyl 9. Insertions of Alkynes into Metal-Carbon Bonds 9. Insertions of Polyenes into Metal-Carbon Bonds Effect of Ancillary Ligands Elimination j3-Hydrogen Elimination from Metal-Silyl Complexes p-Hydrocarbyl Eliminations fi-Alkyl and fi-Aryl Eliminations from Alkoxido and Amido Complexes a-Hydrogen Eliminations and Abstractions 9. Insertions of Olefins into Bonds on the Rate of 3-Hydrogen 9. Insertions of Polyhapto Ligands into Metal- Bonds p-Hydrogen Elimination Metal-Hydride Bonds Effect of Electronics on the Rate of 9.

Insertions of Other Ligands Bound Through a 9. Insertions into Metal-Hydride Coordination Number on the Rate of 9. Catalysis by Lewis Acids Hydride Bonds Effect of Conformation and 9. Catalysis of CO Insertion Hydride Bonds p-Hydrogen Eliminations Complexes 9. Kinetic Effects on Migratory Ligand Covalent Bonds fi-Hydrogen Elimination from Metal-Alkyl 9. Insertions of Carbenes p-Elimination Processes 9. Thermodynamic Effects on Migratory Single Atom Chapter Elimination Reactions Scope of Organometallic Elimination 9. Migratory Aptitudes of R Aptitudes Overview of the Chapter 9. Structure of the Unsaturated Aptitudes References and Notes 9. Solvent Effects into Metal-Silicon and Metal-Boron Intermediate 9. Insertions of Olefins and Acetylenes 9. Insertions into Electron Complexes 9. Insertions of Olefins into Metal-Nitrogen 9. Kinetics and Mechanism of CO Insertions into Metal-Alkyl Complexes Bonds 9.

Insertion of Olefins into Metal-Oxygen 9. Examples of Insertions of CO into 9. Insertions into Electron 9. Insertions of Olefins and Acetylenes into 9. Examples of CO Insertions into Complexes xxiii Summary References and Notes Chapter Nucleophilic Attack on Coordinated Ligands Fundamental Principles Nucleophilic Attack on Transition Metal Complexes of Carbon Monoxide and Isonitriles xiv CONTENTS General Trends Examples of Nucleophilic Attack on Carbon Monoxide and Isonitriles Overview and Basic Principles Nucleophilic Attack On Carbene and Carbyne Complexes Carbon and Metal-Hydride a-Bonds General Principles and Trends Mechanism of Electrophilic Attack Examples of Nucleophilic Attack on a-Bound d-Electrons General Trends Bonds in Complexes Possessing d-Electrons Complexes Metal-Hydride Overview of Nucleophilic Attack on Complexes rf-Olefin Nucleophilic Attack on Square Planar Pd II Electrophilic Insertion Reactions: Sulfur Dioxide, Ligands Attack at the a-Position Attack at the p-Position Nucleophilic Attack on r 4-Diene Complexes Heteroarene Complexes Summary Nucleophilic Attack on irf-Arene and if-Arene Examples of Nucleophilic Attack on ir-Arene References and Notes Overview of Nucleophilic Attack on Complexes Electrophilic Attack on rf-Arene and r 5-Dienyl Complexes Electrophilic Attack on iT-Polyenyl Cycloheptatrienyl Complexes Hydride Abstraction by Electrophilic Attack on Nucleophilic Attack on Electrophilic Modification of Coordinated on Olefin Complexes Nucleophilic Attack on -rf-Allyl References and Notes Attack of Carbonyl Compounds and Protons Complexes Complexes that Lack d-Electrons Attack on Coordinated Olefins and Polyenes Nucleophilic Attack on Polyhapto T 3-T 6 Complexes Mechanism of Electrophilic Attack on Alkyl Complexes Nucleophilic Attack on Imine and Aldehyde Complexes Electrophilic Attack on Carbene and Carbyne Reactions of -rf-Arene Complexes Containing d-Electrons Group Nucleophilic Attack on tf-Alkyne Complexes Bonds in Complexes Carbon Dioxide and Related Electrophiles and Diene and Allene Complexes Mechanism of Protonation of Nucleophilic Attack on i f -Olefin Summary Possessing Mechanism of Protonolysis of Metal-Carbon Ligands Electrophiles on Alkyl Complexes Complexes Mechanism of Attack of Main Group Scope of Electrophilic Cleavage of Metal- Ligands Electrophilic Cleavage of Metal-Carbon and Metal-Hydride a-Bonds Nucleophilic Cleavage of Metal-Carbon a-Bonds Chapter Metal-Ligand Multiple Bonds Introduction to Metal-Ligand Multiple Bonds Carbene Complexes Classes of Carbene Complexes Origin of the Electronic Properties of Fischer and Schrock Carbenes CONTENTS xxiii Synthesis of Carbene Complexes Reactions with C-H Bonds Synthesis of Fischer Carbene Complexes Reactions with Electrophiles from MtoOorN Synthesis of Some Classic Alkylidene Compounds Through Carbene Complexes Intermediates Alkylidene Catalysts Rosenfeld Synthesis of Metal-Nitrido Complexes Reactions of Metal-Nitrido Complexes References and Notes Reactions with NucleophHes Chapter Walsh Conversion to Carbyne Complexes General Principles Reactions Related to Those of Enolates Cyclopropanations Annulations: The Dotz Reaction Reactivity of Vinylidene Complexes Complexes Alkylidenes and Alkylidynes Reaction Coordinate Diagrams of Catalytic Catalyst Precursors, Catalyst and Promoters Deactivation, Quantification of Efficiency Kinetics of Catalytic Reactions and Resting Overview of Silylene Complexes Bonding of Silylene Complexes States Reactivity of Silylene Complexes Metal-Heteroatom Multiple Bonds Bonding of Oxo and Imido Complexes Fundamentals of Asymmetric Catalysis Importance of Asymmetric Catalysis Nomenclature Description of Stereoselectivity Synthesis of Metal-Imido and Metal-Oxo The Origin of Stereoselection Synthesis of Metal-Imido Complexes Energetics of Stereoselectivity Reaction Coordinates of Catalytic Reactions of Imido and Oxo Compounds Classes of Asymmetric Transformations Atom Transfer of Oxo and Imido Groups to Distinguishing Homogeneous from Heterogeneous Catalysts Synthesis of Metal-Oxo Complexes Homogeneous vs.

Heterogeneous Catalysis Examples of Isolated Silylene Complexes The Catalytic Cycle Scope of the Section Energetics of Catalysis Terminology of Catalysis Silylene Complexes Origins of Transition State Stabilization cr-Bonds Definition of a Catalyst Reactions Reactivity of Alkylidene and Alkylidyne Olefins Structural and Spectral Features Reactivity of Fischer Carbene Complexes Bonding of Nitrido Ligands Synthesis of N-Heterocyclic Carbene Overview Synthesis of Tebbe's Reagent Reactivity of Carbene Complexes Organometallic Nitrido Ligands Written with Dr.

Devon C. Synthesis of the Schiock Complexes Catalytic Reactions of Imido and Metal-Oxo Synthesis of the First Schiock Complexes Migrations ofAlkyl and Hydride Groups Synthesis of Vinylidene Complexes Complexes Enantioselective Reactions Reactions with a Single Enantioselectivity-Determining Step XXii CONTENTS Reactions with Reversiblity Prior to Selected Examples of Achiral Homogeneous the Enantioselectivity-Determining Hydrogenation Catalysts Step: The Curtin-Hammett Principle Applied to Asymmetric Catalysis Theory Curtin-Hammett Conditions Asymmetric Hydrogenation Asymmetric Allylic Alkylation Effect of C2 Symmetry Resolutions and Desymmetrizations Directed Hydrogenation Mechanisms of Homogeneous Olefin and Ketone Hydrogenation Background Quantification of Selectivity in Meclwnisms Occurring by Insertions of Energetics of Selectivity in Kinetic Olefins into Dihydride Complexes Hydrogenation by Wilkinson's Examples of Kinetic Catalyst Mechanism of the Oxidative Dynamic Kinetic Resolution Addition Step Example of Dynamic Kinetic Resolution of 1,3-Dicarbonyl Catalysts Containing Aromatic Phosphines Desymmetrization Reactions Cationic Rhodium Catalysts Two Examples of Containing Alkylphosphines Containing Alkylphosphines Catalysts that React by Insertions of Olefins into Monohydride Intermediates Desymmetrization via the PalladiumCatalyzed Heck Reaction Cationic Iridium Catalysts ofAchiral Dienes via Catalytic Asymmetric Hydrosilylation Cationic Rhodium Complexes Dynamic Kinetic Asymmetric Desymmetrization Insertion Step Hydrogenation by Cationic Rhodium Compounds Through Asymmetric Desymmetrization Mechanism of the Migratory Resolutions: Dynamic Kinetic References and Notes Lanthanide Catalysts Alternative Asymmetric Processes: Kinetic The Reactivity of Wilkinson's Hydrogenation Selective Catalysts "Privileged Ligands" Transformations Catalyst Ruthenium Catalysts for Olefin Structures of Ligands Generating Highly Hydrogenation Preparation of Wilkinson's Cationic Rhodium Catalysts Kinetic Resolutions Iridium Catalysts: Crabtree's Catalyst Quadrant Diagrams Resolutions Catalyst Transmission of Asymmetry Resolutions Hydrogenation Neutral Rhodium Catalysts List of Adoptions Errata.

Gray, California Institute of Technology. It is a treasure trove of information that will prove invaluable for both students and practitioners of the field. To anyone who wants to engage in this line of research, this text will serve as the single best source for all the essential information. RajanBabu, The Ohio State University. It should well serve both teachers choosing a textbook for an advanced course and active researchers looking for a good starting reference source. Labinger, California Institute of Technology. John F. Hartwig is the Henry Rapoport Chair in Organic Chemistry and Professor of Chemistry at the University of California, Berkeley. Professor Hartwig received his A. degree from Princeton and his Ph. from the University of California, Berkeley. Subsequently, he was an American Cancer Society Postdoctoral Fellow at the Massachusetts Institute of Technology, joined the Yale University faculty in , and joined the University of Illinois chemistry faculty in July He was one of the originators of palladium-catalyzed cross-coupling reactions to form carbon-heteroatom bonds, as well as palladium-catalyzed coupling of enolates and catalytic functionalization of the terminal C-H bonds in alkanes.

He was elected as a member of the National Academy of Sciences in , was the recipient of the Mukaiyama Award from the Society of Synthetic Organic Chemistry, Japan, the International Catalysis Award from the International Association of Catalysis Societies, the Paul N. Rylander Award of the Organic Reactions Catalysis Society, the Tetrahedron Young Investigator Award in Organic Synthesis, the Raymond and Beverly Sackler Prize in the Physical Sciences, and the ACS Award in Organometallic Chemistry. Share: Share this page on Facebook Share this page on Twitter Share this page on Twitter Pin this page on Pinterest Send this link in an email message.

Organotransition Metal Chemistry — From Bonding to Catalysis provides a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates. Built upon the foundation established by the classic text by Collman, Hegedus, Norton and Finke, this text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. The early chapters describe the principles of bonding and the classes of ligands that characterize organotransition metal chemistry. The remainder of the book focuses on the reactions of organometallic complexes.

The second portion of the book describes the classic stoichiometric organometallic reactions, including ligand substitution, oxidative addition, reductive elimination, migratory insertions, eliminations, electrophilic attack on coordinated ligands, nucleophilic attack on coordinated ligands, and chemistry of metal-ligand multiple bonds. The third portion of the text describes the principles of catalysis and the classic catalytic processes of organometallic systems. List of Adoptions Errata. Gray, California Institute of Technology. It is a treasure trove of information that will prove invaluable for both students and practitioners of the field.

To anyone who wants to engage in this line of research, this text will serve as the single best source for all the essential information. RajanBabu, The Ohio State University. It should well serve both teachers choosing a textbook for an advanced course and active researchers looking for a good starting reference source. Labinger, California Institute of Technology. John F. Hartwig is the Henry Rapoport Chair in Organic Chemistry and Professor of Chemistry at the University of California, Berkeley. Professor Hartwig received his A. degree from Princeton and his Ph. from the University of California, Berkeley. Subsequently, he was an American Cancer Society Postdoctoral Fellow at the Massachusetts Institute of Technology, joined the Yale University faculty in , and joined the University of Illinois chemistry faculty in July He was one of the originators of palladium-catalyzed cross-coupling reactions to form carbon-heteroatom bonds, as well as palladium-catalyzed coupling of enolates and catalytic functionalization of the terminal C-H bonds in alkanes.

He was elected as a member of the National Academy of Sciences in , was the recipient of the Mukaiyama Award from the Society of Synthetic Organic Chemistry, Japan, the International Catalysis Award from the International Association of Catalysis Societies, the Paul N. Rylander Award of the Organic Reactions Catalysis Society, the Tetrahedron Young Investigator Award in Organic Synthesis, the Raymond and Beverly Sackler Prize in the Physical Sciences, and the ACS Award in Organometallic Chemistry. Share: Share this page on Facebook Share this page on Twitter Share this page on Twitter Pin this page on Pinterest Send this link in an email message.

Organotransition Metal Chemistry: From Bonding to Catalysis John Hartwig University of California, Berkeley. Subjects: Chemistry Inorganic Chemistry Organic Chemistry. Book Purchase Options. For Instructors. Summary Table of Contents Reviews Authors. Summary Organotransition Metal Chemistry — From Bonding to Catalysis provides a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates.

Translated into Japanese. Resources List of Adoptions Errata. Table of Contents Chapter 1 Structure and Bonding Chapter 2 Dative Ligands Chapter 3 Covalent Ligands Bound Through Metal-Carbon and Metal-Hydride Bonds Chapter 4 Covalent Ligands Bound Through Metal-Heteroatom Bonds Chapter 5 Ligand Substitution Reactions Chapter 6 Oxidative Addition of Non-Polar Reagents Chapter 7 Oxidative Addition of Polar Reagents Chapter 8 Reductive Elimination Chapter 9 Migratory Insertion Chapter 10 Elimination Reactions Chapter 11 Nucleophilic Attack on Coordinated Ligands Chapter 12 Electrophilic Attack on Coordinated Ligands Chapter 13 Metal-Ligand Multiple Bonds Chapter 14 Principles of Catalysis Chapter 15 Homogenous Hydrogenation Chapter 16 Hydrofunctionalization and Oxidative Functionalization of Olefins Chapter 17 Catalytic Carbonylation Chapter 18 Catalytic C-H Functionalization Chapter 19 Cross Coupling Chapter 20 Allylic Substitution Chapter 21 Catalytic Metathesis of Olefins and Alkynes Chapter 22 Olefin Polymerization.

John Hartwig University of California, Berkeley John F. View Profile.

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13/09/ · University Science Books, Sausalito pp., hardcover, $ —ISBN Organotransition metal chemistry from bonding to catalysis pdf download The book uses the covalent model in describing both bondings made in most organometallic compounds and [PDF] Download Organotransition Metal Chemistry From Bonding to Catalysis Full PDF Online 1. [PDF] Download Organotransition Metal Chemistry: From Bonding to Catalysis Phosphane ligands are well-known in organometallic chemistry and catalysis, and the application of methoxy-substituted triarylphosphanes has also been re- ported, [1] [2] [3] Organotransition Metal Chemistry From Bonding To Catalysis. Download full Organotransition Metal Chemistry From Bonding To Catalysis Book or read online Organotransition Metal Chemistry – From Bonding to Catalysis provides a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the ... read more

Effect of Ancillary Ligands Elimination Amido Complexes of the Early Transition Metals 3. Ring-Expansion Carbonylation of Epoxides Epoxide Carbonylation Copolymerization of CO and Pauson-Khand Reactions Written with Dr. Oxidative Addition of Polar Reagents Chapter 8. This is an amazingly holistic book for organometallic chemistry. Properties of Free Carbenes 1.

Duraj for editing and proofreading. Introduction xxiii Single Metal Center 6. Intermolecular C-H Functionalization by Carbene Insertion Applications of Alkyne Metathesis Synthesis of Complexes Containing Terminal 51 Ligands Prof. Classes of Asymmetric Transformations Hydrosilylation of Olefins with Achiral Catalysts